Method of Defining Pseudocritical Region Based on Secondary Phase Transition Theory
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摘要: 拟临界区通常意义上是指超临界条件下拟临界点附近物性变化剧烈的区域,在该区域内超临界流体的传质、传热行为与亚临界流体有很大不同,传统的亚临界热工水力分析模型已不适用,因此拟临界区是超临界流体热工水力特性研究的重点区域。本文基于拟临界区的热力学性质提出一种新的划分方法,认为超临界条件下高密度流体与低密度流体的转变满足二级相变理论,表面张力消失点为拟临界区的起始点,拟临界温度是相转变点,拟临界区的起始点和终止点满足Ehrenfest相变平衡方程。
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关键词:
- 拟临界区 /
- 二级相变 /
- 表面张力 /
- Ehrenfest方程
Abstract: Pseudocritical region is generally considered as a region where fluid property has a sharp variation near the pseudocritical point under supercritical conditions.The flow and heat transfer mechanism behaves uniquely and traditional subcritical formulas may not be applicable in this area.Many researchers have devoted to investigate its peculiarities.The pseudocritical region is similar to the two-phase subcritical saturation region.However,the pseudocritical region is a vague concept without specific physical definition,which can not borrow and learn the subcritical concepts.In this study,the pseudocritical region is considered as the secondary phase transition process and the point where the surface tension disappears represents the start of the phase change.Moreover,as the phase transition process satisfies the Ehrenfest equation,the end point of phase transition is determined in combination with the start point.The pseudocritical region based on this method could help and make contribution to the investigation of flow and heat transfer mechanism in this area.-
Key words:
- Pseudocritical region /
- Secondary phase transition /
- Surface tension /
- Ehrenfest equation
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