Optimization of Carbonization Process in Manufacture of Fuel Elements for HTGR
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摘要: 采用热失重-红外联用(TG-IR)、差示量热分析(DSC)方法研究高温气冷堆燃料元件基体材料中作为黏结剂的酚醛树脂在20~800℃的分解过程。用热机械分析仪(TMA)分析石墨球样品在20~800℃的动态热膨胀特性。测试结果表明,酚醛树脂在50~70℃的范围内发生相变,在测试温度范围内分解经过2个连续的放热过程,石墨球样品相应地先膨胀后收缩。采用4段炭化制度所制基体材料的压碎强度达到19.9 kN、落球强度在60次以上,各项指标完全满足设计要求,而且炭化工艺生产效率提高71%。研究表明,在动态条件下根据样品尺寸随温度的变化建立的炭化升温制度更为合理;炭化过程中,缩聚反应引起的体积变化是决定升温速率的关键。Abstract: The decomposition process of phenolic resin which is a binder of spherical fuel elements matrix material for high temperature gas-cooled reactor(HTGR) was studied by means of TG-IR and DSC at the temperature of 20~800 ℃.The thermal expansion characteristics of graphite ball samples were investigated through thermal mechanical analysis(TMA).The results showed that the phase transition of the phenolic resin occurred at the temperature of 50~70℃ and the decomposition had two continuous exothermic stages.Accordingly,the graphite ball samples were expanded and shrink successively during carbonization.The properties of the matrix material made through four-stages heating process completely satisfied the design requirements and the production efficiency of carbonization was increased by 71%.Studies showed that the heating process established according to the sample’s size varied with carbonization temperature under dynamic conditions is more reasonable and the volume change caused by condensation is the critical factor to heating rate.
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Key words:
- HTGR /
- Spherical fuel element /
- Carbonization /
- Phenolic resin
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