Austenitic stainless steel welds in PWR main pipe are susceptible to thermal aging embrittlement at reactor operating temperature of 280~325 ℃after a long service life.In order to obtain thermal aging embrittlement of 316 LN austenitic stainless steel weld at reactor operating temperature, In this study, thermal aging embrittlement of types 316 LN austenitic stainless steel weld with 10.7% ferrite was investigated on basis of embrittlement properties after aging up to 6,000 h at 325,365 and 400℃. The result show that,no change in the main alloy elements contents in ferrite and austenite.Large increase in the microhardness of weld was observed with no change in austenite hardness. The impact toughness was significantly degraded after aging.