It is essential for the safe and stable operations of Nuclear Power Plants that various resources in the supply chain are effectively managed. Supplier is a significant resource of nuclear entities serving as an extension of the operation process. Scientific and rational evaluation of the performance of suppliers is of vital importance to an effective and high quality supply chain. This paper establishes an advance and practical supplier evaluation system that is applicable for the operational nuclear power plants, based on the analysis of the current operation status of Daya Bay Nuclear Power Station against its targeted objectives, the acquisition of relevant practices home and abroad and the benchmarking with advanced peers, in order to enhance the core competence of nuclear power plant.