The oxidation and purification of the primary coolant loop is of great importance in control-ling the dose rate during the outage.In this paper,the effects of pH value,H
2O
2 and H
2 concentration on the migration of activated corrosion products were discussed theoretically.A new method for the shutdown oxy-genation operation,characterized by low pH,low H
2 and introducing oxygen densely at suitable amount,was proposed based on the operation experience of Daya Bay nuclear power station.