Study on the Effect of C-ion Irradiation on Hardness and Young's Modulus of Nuclear-grade Graphite
-
摘要: 为了探明离子辐照剂量和辐照温度对核级石墨硬度、杨氏模量及微观组织的影响，采用0.02 dpa 、0.2 dpa和2 dpa剂量的C4+分别在室温和180℃下辐照核级石墨，利用纳米压痕仪和透射电镜对不同离子辐照条件下核级石墨的性能和微观组织进行研究。结果表明：室温辐照时，硬度和杨氏模量均随着辐照剂量的增加而增加，辐照剂量为2 dpa时，硬度与杨氏模量的峰值分别由未辐照时的0.51 GPa与15.52 GPa急剧增加到2.51 GPa与37.73 GPa。180℃辐照剂量为0、0.02、0.2 dpa时，硬度和杨氏模量也随着辐照剂量的增加而增加，均高于室温辐照相同辐照剂量下硬度和杨氏模量的峰值。当辐照剂量达到2 dpa时，硬度与杨氏模量的峰值从0.2 dpa的1.72 GPa和31.53 GPa迅速降为1.32 GPa和25.91 GPa。石墨硬度和杨氏模量的增加是由于辐照导致石墨内部的微裂纹闭合和基体缺陷增加造成的，180℃辐照2 dpa后硬度和杨氏模量的急剧降低是由于辐照导致石墨发生了非晶化导致的。Abstract: In order to ascertain the effect of ion irradiation dose and temperature on the hardness, Young's modulus and microstructure of nuclear-grade graphite, 0.02 dpa, 0.2 dpa and 2 dpa C4+ are used in this paper to irradiate nuclear-grade graphite at room temperature and 180℃, respectively. The properties and microstructure of nuclear-grade graphite under different ion irradiation conditions are studied by using nano indentor and transmission electron microscopy. The results show that the hardness and Young's modulus increase with the increase of irradiation dose at room temperature, when the irradiation dose is 2 dpa, the peak values of hardness and Young's modulus increas sharply from 0.51 GPa and 15.52 GPa without irradiation to 2.51 GPa and 37.73 GPa respectively. When the irradiation dose is 0~0.2 dpa at 180℃, the hardness and Young's modulus increase with the increase of irradiation dose, and they are higher than those at room temperature with the same irradiation dose, when the irradiation dose reaches 2 dpa, the peak values of hardness and Young's modulus decrease rapidly from 1.72 GPa and 31.53 GPa of 0.2 dpa to 1.32 GPa and 25.91 GPa. The increase of the hardness and Young's modulus is due to the micro-crack closure and the increase of matrix defects in graphite caused by irradiation. The sharp decrease of the hardness and Young's modulus at 180℃ is due to the amorphization of graphite structure caused by irradiation.
-
Key words:
- Nuclear-grade graphite /
- Ion irradiation /
- Hardness /
- Young's modulus
-
图 1 1.08 MeV C离子在石墨中产生的损伤
Figure 1. Damage Caused by 1.08 MeV C-Ion Irradiation in Graphite
图 2 室温和180℃辐照前后石墨硬度随压入深度的变化
Figure 2. Variation of Graphite Hardness with Indentation Depth before and after Irradiation at Room Temperature and 180℃
图 3 室温和180℃辐照前后石墨杨氏模量随压痕深度的变化
Figure 3. Variation of Young's Modulus of Graphite with Indentation Depth before and after Irradiation at Room Temperature and 180℃
图 4 石墨硬度与杨氏模量峰值随辐照剂量的变化
Figure 4. Variations of Peak Values of Hardness and Young's Modulus of Graphite with Irradiation Dose
-
[1] 岳维宏,逄锦鑫. 重水研究堆退役废物再利用研究[J]. 原子能科学技术,2013, 47(8): 1398-1404. doi: 10.7538/yzk.2013.47.08.1398 [2] KIM E S, KIM Y W. Characterization of 3 MeV H+ irradiation induced defects in nuclear grade graphite[J]. Solid State Communications, 2010, 150(35-36): 1633-1636. doi: 10.1016/j.ssc.2010.06.036 [3] KRISHNA R, JONES A N, MARSDEN B J. Transmission electron microscopy, Raman and X-ray photoelectron spectroscopy studies on neutron irradiated polycrystalline graphite[J]. Radiation Physics and Chemistry, 2015, 107: 121-127. doi: 10.1016/j.radphyschem.2014.10.005 [4] KRISHNA R, JONES A N, MCDERMOTT L, et al. Neutron irradiation damage of nuclear graphite studied by high-resolution transmission electron microscopy and Raman spectroscopy[J]. Journal of Nuclear Materials, 2015, 467: 557-565. doi: 10.1016/j.jnucmat.2015.10.027 [5] CAMPBELL A A, KATOH Y, SNEAD M A, et al. Property changes of G347A graphite due to neutron irradiation[J]. Carbon, 2016, 109: 860-873. doi: 10.1016/j.carbon.2016.08.042 [6] ISHIYAMA S, BURCHELL T D, STRIZAK J P, et al. The effect of high fluence neutron irradiation on the properties of a fine-grained isotropic nuclear graphite[J]. Journal of Nuclear Materials, 1996, 230(1): 1-7. doi: 10.1016/0022-3115(96)00005-0 [7] KARTHIK C, KANE J, BUTT D P, et al. Neutron irradiation induced microstructural changes in NBG-18 and IG-110 nuclear graphites[J]. Carbon, 2015, 86: 124-131. doi: 10.1016/j.carbon.2015.01.036 [8] HEGGIE M I, SUAREZ-MARTINEZ I, DAVIDSON C, et al. Buckle, ruck and tuck: a proposed new model for the response of graphite to neutron irradiation[J]. Journal of Nuclear Materials, 2011, 413(3): 150-155. doi: 10.1016/j.jnucmat.2011.04.015 [9] BROCKLEHURST J E, KELLY B T. Analysis of the dimensional changes and structural changes in polycrystalline graphite under fast neutron irradiation[J]. Carbon, 1993, 31(1): 155-178. doi: 10.1016/0008-6223(93)90169-B [10] 白新德,王社管,马春来,等. 离子轰击模拟中子辐照在核材料研究中的应用[J]. 原子能科学技术,1996, 30(5): 469-474. [11] 王志光. 利用高能离子模拟研究反应堆结构材料中的辐照效应[J]. 原子核物理评论,2006, 23(2): 155-160. doi: 10.3969/j.issn.1007-4627.2006.02.016 [12] 黄庆,李健健,黄鹤飞,等. 核石墨的氙离子辐照效应[J]. 核动力工程,2017, 38(S1): 67-70. [13] CHANG C K, TSAI S C, KAI J J, et al. A synchrotron X-ray study on the Wigner effect of the irradiated nuclear-grade graphite[J]. Procedia Engineering, 2012, 36: 7-12. doi: 10.1016/j.proeng.2012.03.003 [14] KARTHIK C, KANE J, BUTT D P, et al. In situ transmission electron microscopy of electron-beam induced damage process in nuclear grade graphite[J]. Journal of Nuclear Materials, 2011, 412(3): 321-326. doi: 10.1016/j.jnucmat.2011.03.024 [15] KELLY B T. Physics of graphite [M]. London: Applied Science Publishers, 1981: 116-118. -
下载:
图(6)
计量
- 文章访问数: 314
- HTML全文浏览量: 83
- PDF下载量: 52
- 被引次数: 0
