Advance Search
Volume 44 Issue 4
Aug.  2023
Turn off MathJax
Article Contents
Dai Wei, Jiang Pingting, Chen Peng, He Dongyu. Development and Verification of Ph Calculation Model of in-Containment Refueling Water Storage Tank under Severe Accidents[J]. Nuclear Power Engineering, 2023, 44(4): 259-266. doi: 10.13832/j.jnpe.2023.04.0259
Citation: Dai Wei, Jiang Pingting, Chen Peng, He Dongyu. Development and Verification of Ph Calculation Model of in-Containment Refueling Water Storage Tank under Severe Accidents[J]. Nuclear Power Engineering, 2023, 44(4): 259-266. doi: 10.13832/j.jnpe.2023.04.0259

Development and Verification of Ph Calculation Model of in-Containment Refueling Water Storage Tank under Severe Accidents

doi: 10.13832/j.jnpe.2023.04.0259
  • Received Date: 2022-09-21
  • Rev Recd Date: 2022-11-20
  • Publish Date: 2023-08-15
  • In order to solve the problem of lacking tools for calculating the pH value of in-containment refueling water storage tank in nuclear power plants after the accident, this paper develops a direct modeling and in-time analysis model for pH value calculation. Based on Newton-Raphson method, by establishing the database of physical properties of key items and reactions, and by building a gas-liquid two-phase chemical equilibrium model, a pH value calculation software CalcpH with a complete database, the capability of high radiation calculation and the capability of coupling calculation with accident evolution is developed. The results of CalcpH are compared with the results calculated by ASTEC (a commonly used severe accident analysis software) and PHREEQC (a commonly used chemical equilibrium analysis software). For non-irradiation reactions, the difference between the calculation results of CalcpH and the results of PHREEQC is within 1.3%. For irradiation reactions, the difference between the results of CalcpH and the results of ASTEC is within 2.7%. While comparing the calculation results of CalcpH with experimental results, the difference is within 1%. The reliability of the calculation results is fully proved by software comparison and experimental comparison. Therefore, the numerical calculation model established by CalcpH can be used to predict the pH value of in-containment refueling water storage tank after the accident..

     

  • loading
  • [1]
    郑华. EPR与CPR1000严重事故缓解措施比较[J]. 核科学与工程,2010, 30(3): 250-257.
    [2]
    CLÉMENT B, HANNIET-GIRAULT N, REPETTO G, et al. LWR severe accident simulation: synthesis of the results and interpretation of the first Phebus FP experiment FPT0[J]. Nuclear Engineering and Design, 2003, 226(1): 5-82. doi: 10.1016/S0029-5493(03)00157-2
    [3]
    CRIPPS R C, GÜNTAY S, JÄCKEL B. The PSIodine code: a computer program to model experimental data on iodine and other species in irradiated CsI solutions sparged with argon, air, or nitrous oxide[J]. Nuclear Engineering and Design, 2011, 241(10): 4306-4325. doi: 10.1016/j.nucengdes.2011.08.010
    [4]
    WREN J C, BALL J M. LIRIC 3.2 an updated model for iodine behaviour in the presence of organic impurities[J]. Radiation Physics and Chemistry, 2001, 60(6): 577-596. doi: 10.1016/S0969-806X(00)00385-6
    [5]
    MORIYAMA K, MARUYAMA Y, NAKAMURA H. Kiche: a simulation tool for kinetics of iodine chemistry in the containment of light water reactors under severe accident conditions (Contract research): JAEA-Data/Code 2010-034[R]. Tokai: Japan Atomic Energy Agency, 2011.
    [6]
    FRANK RAHN. MAAP4 - modular accident analysis, nuclear power division: RP3131-02[R]. U. S. : Electric Power Research Institute, 2007
    [7]
    GAUNTT R O, CASH J E, COLE R K, et al. MELCOR computer code manuals vol. 2: reference manuals: NUREG/CR-6119[R]. Washington: U. S. : Nuclear Regulatory Commission, 2005.
    [8]
    COUSIN F. ASTEC V2.2 pH module: Modelling and user manual: IRSN/2016-00117[R]: France: Saint-Paul-Lez-Durance, IRSN, 2016
    [9]
    PARKHURST D L, APPELO C A J. User’s guide to PHREEQC (version 2)-a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations: Water-Resources Investigations Report 99-4259[R]. Denver: U. S. Department of the Interior, 1999.
    [10]
    BEAHM E C, LORENZ R A, WEBER C F. Iodine evolution and pH control: NUREG/CR-5950[R]. Washington: U. S. Nuclear Regulatory Commission, 1992.
    [11]
    WREN J C, BALL J M, GLOWA G A. Studies on the effects of organic-painted surfaces on pH and organic iodide formation: NEA/CSNI/R(99)7[R]. Vantaa, Finland: OECD Workshop on Iodine Aspects of Severe Accident Management, 1999.
    [12]
    BEAHM E C, WEBER C F, KRESS T S, et al. Iodine chemical forms in LWR severe accidents: NUREG/CR-5732[R]. Washington: U. S.: Nuclear Regulatory Commission, 1992.
    [13]
    KEKKI T, ZILLIACUS R. Formation of nitric acid during high gamma dose radiation: VTT-R-00774-11[R]. Finland: VTT Technical Research Centre of Finland, 2011.
    [14]
    LANGMUIR D. Aqueous environmental geochemistry[M]. Upper Saddle River, New Jersey: Prentice Hall, 1997: 600.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(8)  / Tables(1)

    Article Metrics

    Article views (394) PDF downloads(22) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return